Portal de Periódicos da CAPES

Synthesis of allyl and benzyl 4-O-(3,6-di-O-methyl-β-d-glucopyranosyl)-2,3-di-O-methyl-α-l-rhamnopyranoside

1987; Elsevier BV; Volume: 165; Issue: 2 Linguagem: Inglês

10.1016/0008-6215(87)80099-x

1873-426X

Jose R. Mariño-Albernas, Vicente Vérez-Bencomo, Leandro González, Carlos Pérez,

Enzyme Production and Characterization

Condensation of 2,4-di-O-acetyl-3,6-di-O-methyl-α-d-glucopyranosyl bromide with either allyl or benzyl 2,4-di-O-methyl-α-l-rhamnopyranoside in the presence of mercuric cyanide, followed by O-deacetylation, gave the title oligosaccharides in excellent yields.