Oxidation of allylic alcohols by dimethyldioxirane: Competition reaction between epoxidation and C-H insertion
1993; Elsevier BV; Volume: 34; Issue: 52 Linguagem: Inglês
10.1016/s0040-4039(00)61350-3
ISSN1873-3581
AutoresWaldemar Adam, Frank Prechtl, Markus Richter, Alexander K. Smerz,
Tópico(s)Free Radicals and Antioxidants
ResumoEpoxidation of allylic alcohols with dimethyldioxirane is accompanied by oxidation of the hydroxy functionality; thus enone formation increases with decreasing substitution at the CC double bond; nonetheless, selective epoxidation can be obtained by acylation of the alcohol functionality.
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