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A thermal P III -P V rearrangement proceeding by a radical mechanism

1976; Royal Society of Chemistry; Issue: 16 Linguagem: Inglês

10.1039/c39760000663

2050-5639

C. Brown, R. F. Hudson, Anna Maroń, Keith A. F. Record,

Synthesis and characterization of novel inorganic/organometallic compounds

The reaction between oximes and tervalent phosphorus compounds to give the corresponding alkylidenamide [R12P(O)NCR2R3] proceeds through the PIII isomer (R12PO–NCR2R3) which spontaneously rearranges (at least in part) by a radical-cage mechanism.