Some Mechanistic Evidence for an Oxygen Transfer Reaction Accompanied by the Redox-Induced Nitrito-Nitro Linkage Isomerization of Ruthenium Complex Having Nitrosyl, cis -[Ru(NO)(X)(bpy) 2 ] 2+ (X = ONO, NO 2 )

Artigo Revisado por pares

Some Mechanistic Evidence for an Oxygen Transfer Reaction Accompanied by the Redox-Induced Nitrito-Nitro Linkage Isomerization of Ruthenium Complex Having Nitrosyl, cis -[Ru(NO)(X)(bpy) 2 ] 2+ (X = ONO, NO 2 )

1996; Oxford University Press; Volume: 25; Issue: 9 Linguagem: Inglês

10.1246/cl.1996.759

ISSN

1348-0715

Autores

Dai Ooyama, Hirotaka Nagao, Noriharu Nagao, F. Scott Howell, Masao Mukaida,

Tópico(s)

Lanthanide and Transition Metal Complexes

Resumo

Abstract An oxygen transfer between the NO and the ONO ligands occurs in cis-[Ru(NO)(ONO)(bpy)2]2+ when the complex undergoes a redox-induced nitrito-to-nitro linkage isomerization. Such an oxygen transfer does not occur in a themally-induced linkage isomerization reported previously.

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Some Mechanistic Evidence for an Oxygen Transfer Reaction Accompanied by the Redox-Induced Nitrito-Nitro Linkage Isomerization of Ruthenium Complex Having Nitrosyl, cis -[Ru(NO)(X)(bpy) 2 ] 2+ (X = ONO, NO 2 )