Artigo Revisado por pares

A new synthesis of the GPIIb/IIIa receptor antagonist SB-214857-A

2001; Elsevier BV; Volume: 42; Issue: 29 Linguagem: Inglês

10.1016/s0040-4039(01)00843-7

ISSN

1873-3581

Autores

Ian P. Andrews, Richard J. Atkins, Neil F. Badham, Richard K. Bellingham, Gary F. Breen, John Carey, Stephen K. Etridge, Jerome F. Hayes, Nigel Hussain, David O. Morgan, Andrew C. Share, Stephen A. Smith, Timothy C. Walsgrove, Andrew S. Wells,

Tópico(s)

Multiple Myeloma Research and Treatments

Resumo

A new synthesis of lotrafiban SB-214857-A is reported. The key steps are the preparation of racemic (4-methyl-3-oxo-2,3,4,5-tetrahydro-1H-benzo[e][1,4]diazepin-2-yl)-acetic acid methyl ester from 2-nitrobenzyl alcohol, a resolution using an immobilised lipase enzyme and a palladium-catalysed aminocarbonylation reaction.

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