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Synthesis, Structure, and Reactivity of Stable PN Heterocycles with Two and Six Methyleneamine Units: [H 2 CNN(Me)] 2 P(S)(Ph) and [H 2 CNN(Me)] 6 P 3 N 3

1993; Wiley; Volume: 32; Issue: 10 Linguagem: Inglês

10.1002/anie.199314771

1521-3773

Christophe Galliot, Anne‐Marie Caminade, Françoise Dahan, Jean‐Pierre Majoral,

Synthesis and characterization of novel inorganic/organometallic compounds

Angewandte Chemie International Edition in EnglishVolume 32, Issue 10 p. 1477-1479 Communication Synthesis, Structure, and Reactivity of Stable PN Heterocycles with Two and Six Methyleneamine Units: [H2CNN(Me)]2 P(S)(Ph) and [H2CNN(Me)]6P3N3 Christophe Galliot, Christophe Galliot Laboratoire de Chimie de Coordination, du CNRS 205, Route de Narbonne, F-31077 Toulouse Cédex (France), Telefax: Int. code + (61)55 3003Search for more papers by this authorDr. Anne-Marie Caminade, Dr. Anne-Marie Caminade Laboratoire de Chimie de Coordination, du CNRS 205, Route de Narbonne, F-31077 Toulouse Cédex (France), Telefax: Int. code + (61)55 3003Search for more papers by this authorDr. Françoise Dahan, Dr. Françoise Dahan Laboratoire de Chimie de Coordination, du CNRS 205, Route de Narbonne, F-31077 Toulouse Cédex (France), Telefax: Int. code + (61)55 3003Search for more papers by this authorDr. Jean Pierre Majoral, Corresponding Author Dr. Jean Pierre Majoral Laboratoire de Chimie de Coordination, du CNRS 205, Route de Narbonne, F-31077 Toulouse Cédex (France), Telefax: Int. code + (61)55 3003Laboratoire de Chimie de Coordination, du CNRS 205, Route de Narbonne, F-31077 Toulouse Cédex (France), Telefax: Int. code + (61)55 3003Search for more papers by this author Christophe Galliot, Christophe Galliot Laboratoire de Chimie de Coordination, du CNRS 205, Route de Narbonne, F-31077 Toulouse Cédex (France), Telefax: Int. code + (61)55 3003Search for more papers by this authorDr. Anne-Marie Caminade, Dr. Anne-Marie Caminade Laboratoire de Chimie de Coordination, du CNRS 205, Route de Narbonne, F-31077 Toulouse Cédex (France), Telefax: Int. code + (61)55 3003Search for more papers by this authorDr. Françoise Dahan, Dr. Françoise Dahan Laboratoire de Chimie de Coordination, du CNRS 205, Route de Narbonne, F-31077 Toulouse Cédex (France), Telefax: Int. code + (61)55 3003Search for more papers by this authorDr. Jean Pierre Majoral, Corresponding Author Dr. Jean Pierre Majoral Laboratoire de Chimie de Coordination, du CNRS 205, Route de Narbonne, F-31077 Toulouse Cédex (France), Telefax: Int. code + (61)55 3003Laboratoire de Chimie de Coordination, du CNRS 205, Route de Narbonne, F-31077 Toulouse Cédex (France), Telefax: Int. code + (61)55 3003Search for more papers by this author First published: October 1993 https://doi.org/10.1002/anie.199314771Citations: 19AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Since it remains unchanged after several days in air and several months under H2O-free argon, the hydrazone 1 is unexpectedly stable; however, methyleneamines RNCH2 rapidly di-, tri-, or polymerize. Compound 1 reacts with (iPr2N)CF3SO as an imine not as a hydrazone-and affords the cationic heterocycles 2 and 3 (counterion is CF3). Citing Literature Volume32, Issue10October 1993Pages 1477-1479 RelatedInformation