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Activity coefficients at infinite dilution measurements for organic solutes and water in the ionic liquid 4-methyl-N-butyl-pyridinium bis(trifluoromethylsulfonyl)-imide

2009; Elsevier BV; Volume: 41; Issue: 12 Linguagem: Inglês

10.1016/j.jct.2009.06.011

1096-3626

Urszula Domańska, Andrzej Marciniak,

Chemical and Physical Properties in Aqueous Solutions

The activity coefficients at infinite dilution, γ13∞ for 36 solutes: alkanes, cycloalkanes, alkenes, alkynes, aromatic hydrocarbons, alcohols, thiophene, tetrahydrofuran, ethers, acetone, and water in the ionic liquid 4-methyl-N-butyl-pyridinium bis(trifluoromethylsulfonyl)-imide [bmPY][NTf2] were determined by gas–liquid chromatography at temperatures from 298.15 K to 368.15 K. The partial molar excess enthalpies at infinite dilution values ΔH1E,∞ were calculated from the experimental γ13∞ values obtained over the temperature range. The selectivity for different separation problems were calculated from the γ13∞ and compared to the literature values for other ionic liquids, N-methyl-2-pyrrolidinone (NMP) and sulfolane.