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BIBTEX RIS

In situ high pressure NMR study of the direct synthesis of NaAlH4

2013; Royal Society of Chemistry; Volume: 15; Issue: 17 Linguagem: Inglês

10.1039/c3cp50777g

ISSN

1463-9084

Autores

Terry D. Humphries, Derek Birkmire, Bjørn C. Hauback, G. Sean McGrady, Craig M. Jensen,

Tópico(s)

Ammonia Synthesis and Nitrogen Reduction

Resumo

The direct synthesis of NaAlH4 has been studied, for the first time, by in situ27Al and 23Na wide-line NMR spectroscopy using high pressure NMR apparatus. Na3AlH6 formation is observed within two minutes of hydrogen addition, while NaAlH4 is detected after a total of four minutes. This indicates the formation of the hexahydride does not proceed to completion before the formation of the tetrahydride ensues.

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