1-Ethoxyvinyl acetate as a novel, highly reactive, and reliable acyl donor for enzymatic resolution of alcohols
1996; Elsevier BV; Volume: 37; Issue: 41 Linguagem: Inglês
10.1016/0040-4039(96)01658-9
ISSN1873-3581
AutoresYasuyuki Kita, Yasushi Takebe, Kenji Murata, Tadaatsu Naka, Shuji Akai,
Tópico(s)Biofuel production and bioconversion
Resumo1-Ethoxyvinyl acetate 3 was found to be a high performance acyl donor for enzymatic resolution of alcohols featuring that (i) 3 shows high reactivity and high selectivity comparable to the most widely used vinyl acetate 1 and (ii) reaction of 3 generates low reactivity ethyl acetate 6 as a single side product, while that of 1 releases unfavorable acetaldehyde 4.
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