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The First 2 H ‐Phosphirene

1987; Wiley; Volume: 26; Issue: 12 Linguagem: Inglês

10.1002/anie.198712571

1521-3773

Oliver Wagner, Gerhard Maas, Manfred Regitz,

Organometallic Complex Synthesis and Catalysis

Angewandte Chemie International Edition in EnglishVolume 26, Issue 12 p. 1257-1259 Communication The First 2H-Phosphirene† Dipl.-Chem. Oliver Wagner, Dipl.-Chem. Oliver Wagner Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-6750 Kaiserslautern (FRG)Search for more papers by this authorProf. Dr. Gerhard Maas, Prof. Dr. Gerhard Maas Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-6750 Kaiserslautern (FRG)Search for more papers by this authorProf. Dr. Manfred Regitz, Corresponding Author Prof. Dr. Manfred Regitz Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-6750 Kaiserslautern (FRG)Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-6750 Kaiserslautern (FRG)Search for more papers by this author Dipl.-Chem. Oliver Wagner, Dipl.-Chem. Oliver Wagner Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-6750 Kaiserslautern (FRG)Search for more papers by this authorProf. Dr. Gerhard Maas, Prof. Dr. Gerhard Maas Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-6750 Kaiserslautern (FRG)Search for more papers by this authorProf. Dr. Manfred Regitz, Corresponding Author Prof. Dr. Manfred Regitz Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-6750 Kaiserslautern (FRG)Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-6750 Kaiserslautern (FRG)Search for more papers by this author First published: December 1987 https://doi.org/10.1002/anie.198712571Citations: 41 † Phosphorus Compounds with Unusual Coordinations, Part 27. This work was supported by the Fonds der Chemischen Industrie and the Deutsche Forschungsgemeinschaft—Part 26: U. Annen, M. Regitz, Tetrahedron Lett. 28 (1987) 5141. AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract In phosphirenes the bonding situation is the opposite of that found in azirines: Whereas the 1Hderivatives are stable in the former, it is the 2Hderivatives which are stable in the latter. The first 2H-phosphirene 3 has sbeen obtained along with 2 by photolysis of the 3H-1,2,4-diazaphospate in pentane at −40°C. An X-ray structure analysis of the "end-on" complex 4 revealed that the P-C bond is remarkably short (1.634(4)%Å). Citing Literature Volume26, Issue12December 1987Pages 1257-1259 RelatedInformation