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Correlation of the anodic peak potentials with the quantum mechanical properties of various vinyl compounds

1987; Elsevier BV; Volume: 237; Issue: 2 Linguagem: Inglês

10.1016/0022-0728(87)85232-4

2590-2954

Hayriye Yilmaz, Levent Toppare, E. Yurtsever,

Metal complexes synthesis and properties

Abstract The anodic peak potentials, E p,a of various vinyl compounds were measured by cyclic voltammetry. The measurements were made in the acetonitrile-tetrabutylammonium fluoroborate system versus a Ag 0 Ag + (0.01 M ) reference electrode. The measured potentials were correlated to π-orbital energies and bond orders calculated by semi-empirical SCF MO methods. A linear correlation was obtained.