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Persistent halogenated compounds in black guillemots (Cepphus grylle) from Greenland––levels, compound patterns and spatial trends

2003; Elsevier BV; Volume: 48; Issue: 1-2 Linguagem: Inglês

10.1016/s0025-326x(03)00369-2

1879-3363

Katrin Vorkamp, Jan H. Christensen, Marianne Glasius, Frank F. Rigét,

Bee Products Chemical Analysis

Twenty-seven black guillemot eggs and 39 livers were analysed for polychlorinated biphenyls (PCBs), chlorinated pesticides including chlordane-related compounds and toxaphene, and polybrominated diphenylethers (PBDEs). The samples were collected at Qeqertarsuaq (Godhavn, West Greenland) and Ittoqqortoormiit (Scoresbysund, East Greenland). The concentrations of halogenated organic compounds in samples from East Greenland were somewhat higher than the corresponding concentrations from West Greenland. Differences in compound patterns were found between West and East Greenland, with higher percentages of the heavier PCB molecules, p,p(')-DDE and alpha-HCH in the samples from Ittoqqortoormiit. Similarly, different levels and different compositions were observed for eggs and livers. The eggs had generally higher concentrations of all compounds as well as higher percentages of CHB-50, CHB-62 and alpha-HCH than liver samples from the same area. Dividing the liver samples into age groups revealed increasing concentrations with age.