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Concentrations of brominated flame retardants in dust from United Kingdom cars, homes, and offices: Causes of variability and implications for human exposure

2008; Elsevier BV; Volume: 34; Issue: 8 Linguagem: Inglês

10.1016/j.envint.2008.05.001

1873-6750

Stuart Harrad, Catalina Ibarra, Mohamed Abou‐Elwafa Abdallah, Rachel Boon, Hugo Neels, Adrian Covaci,

Carcinogens and Genotoxicity Assessment

Average concentrations of polybrominated diphenyl ethers (PBDEs) in dust in 30 homes, 18 offices, and 20 cars were 260,000, 31,000, and 340,000 ng ΣPBDEs g- 1 respectively. Concentrations of BDEs 47, 99, 100, and 154 in cars exceeded significantly (p < 0.05) those in homes and offices. Average concentrations of 1,2-bis(2,4,6-tribromophenoxy)ethane (TBE) and decabromodiphenyl ethane (DBDPE) in homes, offices, and cars respectively were lower at 120, 7.2, and 7.7 ng g− 1 (TBE) and 270, 170, and 400 ng g− 1 (DBDPE). BDE-209 concentrations in three samples are the highest to date at 2,600,000 (car), 2,200,000 (home), and 1,400,000 ng g− 1 (home). UK toddlers daily consuming 200 mg dust contaminated at the 95th percentile concentration, ingest 180 ng Σtri-hexa-BDEs and 310 μg BDE-209 day− 1. For TBE, exposure was lower than for PBDEs and hexabromocyclododecanes (HBCDs), while that for DBDPE was similar in magnitude to Σtri-hexa-BDEs, but less than for BDE-209 and HBCDs. BDE-209 concentrations recorded in ten samples taken at monthly intervals in one room varied 400-fold, implying caution when using single measurements of dust contamination for exposure assessment. Significant negative correlation was observed in one room between concentrations of BDE-47, 99, and 153 and dust loading (g dust m− 2 floor), suggesting “dilution” occurs at higher dust loadings.