OH−O and CH−O Hydrogen Bonding in Hydrated Crystals of Paramagnetic [(η 6 -C 6 H 6 ) 2 Cr] +
1996; American Chemical Society; Volume: 15; Issue: 4 Linguagem: Inglês
10.1021/om950611d
ISSN1520-6041
AutoresDario Braga, Anna Luisa Costa, Fabrizia Grepioni, Laura Scaccianoce, Emilio Tagliavini,
Tópico(s)Advanced Chemical Physics Studies
ResumoThe hydrated crystalline species [(η6-C6H6)2Cr][OH]·3H2O and [(η6-C6H6)2Cr][CHD]·3H2O (CHD = 1,3-cyclohexanedione) have been prepared and structurally characterized, showing that OH−O as well as CH−O hydrogen bonds involving the water molecules are responsible for crystal cohesion.
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