New Fused Bicyclic Cyclotrigermanes from Cycloaddition Reactions of Cyclotrigermene
2000; Wiley; Volume: 39; Issue: 21 Linguagem: Inglês
10.1002/1521-3773(20001103)39
ISSN1521-3773
AutoresNorihisa Fukaya, Masaaki Ichinohe, Akira Sekiguchi,
Tópico(s)Organometallic Complex Synthesis and Catalysis
ResumoThe mesityl-substituted cyclotrigermene 1 underwent [2+4] cycloaddition with isoprene and 2,3-dimethyl-1,3-butadiene to yield 1,6,7-trigerma-7-mesitylbicyclo[4.1.0]hept-3-ene derivatives 2, and [2+2] cycloaddition with phenylacetylene to yield 1,4,5-trigerma-5-mesityl-2-phenylbicyclo[2.1.0]pent-2-ene (3).
Referência(s)