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Artigo Revisado por pares
BIBTEX RIS

Terminal chloroaminophosphido and aminophosphinidene complexes of molybdenum

2001; Elsevier BV; Volume: 617-618; Linguagem: Inglês

10.1016/s0022-328x(00)00709-9

ISSN

1872-8561

Autores

B.T. Sterenberg, Arthur J. Carty,

Tópico(s)

Organometallic Complex Synthesis and Catalysis

Resumo

The phosphido complex [Cp*Mo(CO)3P(Cl)NiPr2] (1, Cp*=C5(CH3)5) was formed by the reaction of Li[Cp*Mo(CO)3] with iPr2NPCl2. Chloride abstraction from 1 leads to the aminophosphinidene complex [Cp*(CO)3MoPNiPr2][AlCl4] (2) which reacts with phenylacetylene to form the metalaphosphacyclobutene complex [Cp*(CO)3Mo{P(NiPr2)C(Ph)CH}][AlCl4] (3).

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