The use of camphor-grown carbon nanotube array as an efficient field emitter
2007; Elsevier BV; Volume: 45; Issue: 9 Linguagem: Inglês
10.1016/j.carbon.2007.04.023
ISSN1873-3891
AutoresMukul Kumar, T. Okazaki, Mineo Hiramatsu, Yukio Ando,
Tópico(s)Mechanical and Optical Resonators
ResumoThree-dimensional growth of well-aligned high-purity multiwall carbon nanotubes (CNTs) is achieved on silicon, nickel-coated silicon and cobalt-coated silicon substrates by thermal decomposition of a botanical carbon source, camphor, with different catalyst concentrations. Field emission study of as-grown nanotubes in a parallel-plate diode configuration suggests them to be an efficient emitter with a turn-on field of ∼1 V/μm (for 10 μA/cm2) and a threshold field of ∼4 V/μm (for 10 mA/cm2). Maximum current density lies in a range of 20–30 mA/cm2 at 5.6 V/μm with significant reversibility. Prolonged stability test of camphor-grown CNT emitters suggests a life time of ∼5 months under continuous operation. A new feature, metal-assisted electron emission from CNTs, has been addressed. Isolated nanotubes used as a cold cathode in a field emission microscope reveal the pentagonal emission sites and hence the atomic structure of the nanotube tips.
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