Voltar
Artigo Revisado por pares
BIBTEX RIS

The Jacobsen–Katsuki Epoxidation and Its Controversial Mechanism

1997; Wiley; Volume: 36; Issue: 19 Linguagem: Inglês

10.1002/anie.199720601

ISSN

1521-3773

Autores

Torsten Linker,

Tópico(s)

Chemical Synthesis and Reactions

Resumo

Radicals or manganaoxetanes–what are the intermediates in the Jacobsen–Katsuki epoxidation (see scheme on the right)? Recent investigations have shown that the mechanism of the epoxidation is strongly dependent on the substitutents of the alkene and on the reaction conditions.

Referência(s)