Chiral rhodium complexes as catalysts in Diels–Alder reactions
1996; Royal Society of Chemistry; Issue: 10 Linguagem: Inglês
10.1039/cc9960001247
ISSN1364-548X
AutoresDaniel Carmona, Carlos Cativiela, Ricardo García-Correas, Fernando J. Lahoz, M.P. Lamata, José A. López, Pilar López, Luis A. Oro, Emilio San José, Fernando Viguri,
Tópico(s)Cyclopropane Reaction Mechanisms
ResumoThe first rhodium enantioselective catalysts for the Diels–Alder reaction between methacrolein and cyclopentadiene are described; the molecular structure of the catalyst precursor [(η5-C5Me5)Rh(R-Prophos)(H2O)][SbF6]2 is also presented.
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