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Sorption−Desorption Behavior of Bispyrazolato−Copper(II) 1D Coordination Polymers

2005; American Chemical Society; Volume: 127; Issue: 17 Linguagem: Inglês

10.1021/ja050856+

1943-2984

Augusto Cingolani, Simona Galli, Norberto Masciocchi, Luciano Pandolfo, Claudio Pettinari, Angelo Sironi,

Magnetism in coordination complexes

A new polycrystalline vapochromic polymorph of the one-dimensional copper bispyrazolate polymer reversibly and selectively absorbs a number of small molecules; the crystal structures of the anhydrous and fully hydrated species, determined by powder diffraction methods, are markedly different despite their simple, fast, and reversible interconversion.