Portal de Periódicos da CAPES

[Bis{(η 5 ‐pentamethylcyclopentadienyl)cobalt}‐μ‐(η 4 :η‐arene)]: Synthesis, Structure, and Unusual Reactivity of a New Type of Triple‐Decker with Bridging Arene Ligands

1995; Wiley; Volume: 34; Issue: 5 Linguagem: Inglês

10.1002/anie.199505921

1521-3773

Jörg J. Schneider, Uwe Denninger, O. Heinemann, Carl Krüger,

Metal-Catalyzed Oxygenation Mechanisms

Angewandte Chemie International Edition in EnglishVolume 34, Issue 5 p. 592-595 Communication [Bis{(η5-pentamethylcyclopentadienyl)cobalt}-μ-(η4:η-arene)]: Synthesis, Structure, and Unusual Reactivity of a New Type of Triple-Decker with Bridging Arene Ligands†‡ Priv.-Doz. Dr. Jörg J. Schneider, Corresponding Author Priv.-Doz. Dr. Jörg J. Schneider Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (FRG)Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (FRG)Search for more papers by this authorDr. Uwe Denninger, Dr. Uwe Denninger Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (FRG) Crystal structure analyses.Search for more papers by this authorDipl.-Chem. Oliver Heinemann, Dipl.-Chem. Oliver Heinemann Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (FRG) Crystal structure analyses.Search for more papers by this authorProf. Dr. Carl Krüger, Prof. Dr. Carl Krüger Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (FRG) Crystal structure analyses.Search for more papers by this author Priv.-Doz. Dr. Jörg J. Schneider, Corresponding Author Priv.-Doz. Dr. Jörg J. Schneider Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (FRG)Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (FRG)Search for more papers by this authorDr. Uwe Denninger, Dr. Uwe Denninger Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (FRG) Crystal structure analyses.Search for more papers by this authorDipl.-Chem. Oliver Heinemann, Dipl.-Chem. Oliver Heinemann Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (FRG) Crystal structure analyses.Search for more papers by this authorProf. Dr. Carl Krüger, Prof. Dr. Carl Krüger Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (FRG) Crystal structure analyses.Search for more papers by this author First published: March 20, 1995 https://doi.org/10.1002/anie.199505921Citations: 37 † We thank Dr. A. Rufinska for recording the solid state 13C NMR spectra and Prof. Dr. P. Binger and Dr. F. Sandmeyer for a sample of the adamant-1-yl-methylidenephosphine. J. J. S. thanks the Deutsche Forschungsgemeinschaft for granting a Heisenberg Fellowship, and the Fonds der Chemischen Industrie for additional financial support. Abbreviations used: Cp = cyclopentadienyl, Cp* = pentamethylcyclopentadienyl, acac = acetylacetonate ‡ Dedicated to Professor Günther Wilke on the occasion of his 70th birthday AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract A μ-η4:η4-arene bridge was detected for the first time in the triple-deckers 1 (arene = benzene, toluene, o-, m-, p-xylene, cumene). This bridging ligand deviates substantially from planarity in the X-ray crystal structure analysis of the cumene derivative (see picture) and is already substitutionally labile at room temperature. It can be exchanged for other π-perimeter compounds without affecting the molecular structure. Citing Literature Volume34, Issue5March 20, 1995Pages 592-595 RelatedInformation