Die Synthese von Aldehyden und Ketonen mit Amidchloriden und V ILSMEIER ‐Reagenzien
1959; Wiley; Volume: 42; Issue: 5 Linguagem: Inglês
10.1002/hlca.19590420527
ISSN1522-2675
AutoresHans Heinrich Bosshard, H. ZOLLINGER,
Tópico(s)Asymmetric Synthesis and Catalysis
ResumoAbstract The constitution of amide chlorides and reaction products of amides with phosphoroxychloride is discussed. Based on infrared spectra and reaction behaviour an ionized constitution is proposed. The mechanism of V ILSMEIER 's aldehyde synthesis is studied. Under certain conditions this reaction can be extended to the synthesis of ketones.
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