Rearrangements of 6-methoxycarbonyl 7-oxabicyclo[2.2.1]hept-2-enes under prévost's reaction conditions
1987; Elsevier BV; Volume: 28; Issue: 33 Linguagem: Inglês
10.1016/s0040-4039(00)96407-4
ISSN1873-3581
AutoresMalcolm M. Campbell, M. Sainsbury, Robert West,
Tópico(s)Chemical synthesis and alkaloids
ResumoThe rearrangement of 7-oxabicyclo[2.2.1]hept-2-enes to 2-oxabicyclo[2.2.1]heptane derivatives, when reacted with iodine and silver acetate, provides further insight into the migratory preferences of alkyl groups involved in Wagner-Meerwein 1,2-bond shifts in unbiased situations.
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