Synthesis and oxidation reactions of a user- and eco-friendly hypervalent iodine reagent
2002; Elsevier BV; Volume: 43; Issue: 4 Linguagem: Inglês
10.1016/s0040-4039(01)02217-1
ISSN1873-3581
AutoresArun P. Thottumkara, Thottumkara K. Vinod,
Tópico(s)Synthesis and Catalytic Reactions
ResumoAllylic and benzylic alcohols are cleanly oxidized to the corresponding carbonyl compounds in water or water–THF mixtures using a water-soluble derivative of o-iodoxybenzoic acid. A mechanism involving single electron transfer steps is proposed for this facile and eco-friendly oxidation protocol.
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