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Molecular Recognition of a Three‐Way DNA Junction by a Metallosupramolecular Helicate

2006; Wiley; Volume: 45; Issue: 8 Linguagem: Inglês

10.1002/anie.200503822

1521-3773

Aneta Oleksi, Alexandre G. Blanco, D. Roeland Boer, Isabel Usón, Joan Aymamı́, Alison Rodger, Michael J. Hannon, Miquel Coll,

RNA and protein synthesis mechanisms

Three point turn: A metallosupramolecular helicate with trigonal-antiprismatic geometry fits perfectly into the central hydrophobic cavity of a three-way DNA junction allowing a new mode of DNA recognition.