Artigo Revisado por pares

Bismuth(III) Chloride (BiCl 3 ); An Efficient Catalyst for Mild, Regio- and Stereoselective Cleavage of Epoxides with Alcohols, Acetic Acid and Water

2000; Taylor & Francis; Volume: 30; Issue: 13 Linguagem: Inglês

10.1080/00397910008086878

ISSN

1532-2432

Autores

Iraj Mohammadpoor‐Baltork, Shahram Tangestaninejad, Hamid Aliyan, Valiollah Mirkhani,

Tópico(s)

Oxidative Organic Chemistry Reactions

Resumo

Abstract Epoxides can be cleaved in a regio- and stereoselective manner with alcohols, acetic acid and water in the presence of catalytic amounts of bismuth(III) chloride, affording the corresponding β-alkoxy and β-acetoxy alcohols and diols in high yields.

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