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Synthesis of PS(PEO)3 star block copolymers from a heterotetrafunctional initiator

2007; Wiley; Volume: 45; Issue: 17 Linguagem: Inglês

10.1002/pola.22147

1099-0518

Olfa Glaied, Christelle Delaite, Philippe Dumas,

Synthetic Organic Chemistry Methods

Journal of Polymer Science Part A: Polymer ChemistryVolume 45, Issue 17 p. 4179-4183 Note Synthesis of PS(PEO)3 star block copolymers from a heterotetrafunctional initiator O. Glaied, O. Glaied Laboratoire de Chimie Macromoléculaire, ENSCMu, 3 rue A. Werner, 68093 Mulhouse Cedex, FranceSearch for more papers by this authorC. Delaite, Corresponding Author C. Delaite [email protected] Laboratoire de Chimie Macromoléculaire, ENSCMu, 3 rue A. Werner, 68093 Mulhouse Cedex, FranceLaboratoire de Chimie Macromoléculaire, ENSCMu, 3 rue A. Werner, 68093 Mulhouse Cedex, FranceSearch for more papers by this authorP. Dumas, P. Dumas Laboratoire de Chimie Macromoléculaire, ENSCMu, 3 rue A. Werner, 68093 Mulhouse Cedex, FranceSearch for more papers by this author O. Glaied, O. Glaied Laboratoire de Chimie Macromoléculaire, ENSCMu, 3 rue A. Werner, 68093 Mulhouse Cedex, FranceSearch for more papers by this authorC. Delaite, Corresponding Author C. Delaite [email protected] Laboratoire de Chimie Macromoléculaire, ENSCMu, 3 rue A. Werner, 68093 Mulhouse Cedex, FranceLaboratoire de Chimie Macromoléculaire, ENSCMu, 3 rue A. Werner, 68093 Mulhouse Cedex, FranceSearch for more papers by this authorP. Dumas, P. Dumas Laboratoire de Chimie Macromoléculaire, ENSCMu, 3 rue A. Werner, 68093 Mulhouse Cedex, FranceSearch for more papers by this author First published: 17 July 2007 https://doi.org/10.1002/pola.22147Citations: 7Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Well-defined amphiphilic PS(PEO)3 star block copolymers have been obtained for the first time through the use of a new partially protected heterotetrafunctional initiator, by coupling ATRP of styrene and anionic Ring-Opening Polymerization (ROP) of EO. This two-step synthesis implies first the obtaining of a PS macroinitiator with three alcohols of same reactivity for the growth of three PEO blocks. REFERENCES AND NOTES 1For example (a) Riess, G.; Dumas, P.; Hurtrez, G. In MML Series, Vol 5: Dendrimers, Assemblies, Nanocomposites; R. Arshady; A. Guyot, Eds.; Citus Books: London, 2002; p 70; Google Scholar(b) Riess, G. Prog Polym Sci 2003, 28, 1107. 10.1016/S0079-6700(03)00015-7 CASWeb of Science®Google Scholar 2 Teyssié, Ph.; Jérôme, R. Polym Prepr (Am Chem Soc Div Polym Chem) 1979, 20, 344. Google Scholar 3 Xie, H.; Xia, J. 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