A structurally characterized dichloro-manganese(IV) complex capable of halogenating alkenes

1995; Royal Society of Chemistry; Issue: 19 Linguagem: Inglês

10.1039/c39950002015

ISSN

2050-5639

Autores

Neil A. Law, Timothy E. Machonkin, Joel P. McGorman, Erlund J. Larson, Jeff W. Kampf, Vincent L. Pecoraro,

Tópico(s)

Catalytic C–H Functionalization Methods

Resumo

MnIV(salpn)Cl2 regioselectively trans-halogenates alkenes in a reaction for which the Mn-containing product is also identified; this is the first Mn-based halogenating system for which the reactive and final Mn-containing products are structurally characterized.

Referência(s)