The preparation and X-ray structure of [M{SePPh2)2N}2], M = Ni, Pd, Pt
1997; Elsevier BV; Volume: 16; Issue: 16 Linguagem: Inglês
10.1016/s0277-5387(97)00040-5
ISSN1873-3719
AutoresChristos Papadimitriou, Panagiotis Veltsistas, Josef Novosad, Raymundo Cea‐Olivares, Rubén A. Toscano, Patricia García‐Domínguez, Marcela Lopez-Cardosa, Alexandra M. Z. Slawin, J. Derek Woollins,
Tópico(s)Metal complexes synthesis and properties
ResumoReaction of [Ni(CH3CO)2]4H2O, H2PdCl4 or H2PtCl6 with HN[P(Se)Ph2]2 in water/acetone gave the title compounds in good yield. The compounds were characterised by IR/Raman, NMR and X-ray crystallography. The square planar metal centres form parts of spiro pseudo-boat rings. The X-ray structures allow comparison of the radii of Pt and Pd atoms.
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