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BIBTEX RIS

Thioether S-ligation in a side-on μ-η 2 :η2-peroxodicopper(ii) complex

2009; Royal Society of Chemistry; Volume: 46; Issue: 1 Linguagem: Inglês

10.1039/b918616f

ISSN

1364-548X

Autores

Ga Young Park, Yunho Lee, Dong-Heon Lee, Julia S. Woertink, Amy A. Sarjeant, Edward I. Solomon, Kenneth D. Karlin,

Tópico(s)

Magnetism in coordination complexes

Resumo

[(ANS)CuI(CH3CN)]+ reacts with O2 giving [{(ANS)CuII}2(μ-η2:η2-O22−)]2+, νO–O = 731 cm−1, shown to possess S-thioether ligation, based on comparisons with analogues having all N-ligands or a –S(Ph) group. The finding is a rare occurrence and new for side-on O22− binding.

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