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Synthesis of Amine−Borane Intramolecular Complexes through Palladium-Catalyzed Rearrangement of Ammonioalkynyltriarylborates

2008; American Chemical Society; Volume: 10; Issue: 6 Linguagem: Inglês

10.1021/ol8001305

1523-7060

Naoki Ishida, Mizuna Narumi, Masahiro Murakami,

Radical Photochemical Reactions

The palladium-catalyzed rearrangement reaction of alkynyltriarylborates having a tertiary ammonium moiety stereoselectively afforded amine-borane intramolecular complexes, some of which exhibited significantly strong fluorescence.