Artigo Revisado por pares

A molecular dynamic calculation of the structure of B2O3 glass

1980; American Institute of Physics; Volume: 73; Issue: 8 Linguagem: Inglês

10.1063/1.440632

ISSN

1520-9032

Autores

Thomas F. Soules,

Tópico(s)

Crystal Structures and Properties

Resumo

A molecular dynamic calculation on vitreous B2O3 reveals a structure in which boron is trigonally coordinated to oxygen. Boron atoms are at the center of approximately regular triangles. The triangles are connected at apices to form a three-dimensional network of interconnected ribbons and sheets. No tendency to form boroxol groups is found and a reinterpretation of the x-ray data of Mozzi and Warren is suggested. A comparison is made with the molecular dynamic structure of silica.

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