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[Cp*Fe(η5-P5)] as a Useful Source for the Synthesis of Cobalt Complexes with “Naked” Pn Ligands

1998; Wiley; Volume: 4; Issue: 10 Linguagem: Inglês

10.1002/(sici)1521-3765(19981002)4

1521-3765

Otto J. Scherer, Sascha Weigel, Gotthelf Wolmershäuser,

Asymmetric Hydrogenation and Catalysis

Chemistry – A European JournalVolume 4, Issue 10 p. 1910-1916 Full Paper [Cp*Fe(η5-P5)] as a Useful Source for the Synthesis of Cobalt Complexes with “Naked” Pn Ligands Otto J. Scherer, Otto J. Scherer oscherer@rhrk.uni-kl.de Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-67663 Kaiserslautern (Germany), Fax: (+49) 631–205–2187Search for more papers by this authorSascha Weigel, Sascha Weigel Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-67663 Kaiserslautern (Germany), Fax: (+49) 631–205–2187Search for more papers by this authorGotthelf Wolmershäuser, Gotthelf Wolmershäuser Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-67663 Kaiserslautern (Germany), Fax: (+49) 631–205–2187Search for more papers by this author Otto J. Scherer, Otto J. Scherer oscherer@rhrk.uni-kl.de Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-67663 Kaiserslautern (Germany), Fax: (+49) 631–205–2187Search for more papers by this authorSascha Weigel, Sascha Weigel Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-67663 Kaiserslautern (Germany), Fax: (+49) 631–205–2187Search for more papers by this authorGotthelf Wolmershäuser, Gotthelf Wolmershäuser Fachbereich Chemie der Universität, Erwin-Schrödinger-Strasse, D-67663 Kaiserslautern (Germany), Fax: (+49) 631–205–2187Search for more papers by this author First published: 14 December 1998 https://doi.org/10.1002/(SICI)1521-3765(19981002)4:10 3.0.CO;2-ECitations: 36AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract A rich diversity of CpRCo complexes with “naked” Pn ligands is obtained upon treatment of [Cp*Fe(η5-P5)] (1) with [CpRCo(CO)2], CpR = C5H4tBu, C5H3tBu2-1,3. Besides the “triple decker” (shown right) with a planar CoP4 middle deck, clusters with trigonal bipyramidal and cubanelike Co3P2, Co4P4, and FeCo2P5 skeletons have been synthesized. The hitherto unknown μ4-η5:η2:η2:η1-coordination mode of the cyclo-P5 ligand in the complex [{Cp*′FeP5}{Co3Cp3R(CO)2}] has been realised. The coordinative stabilization of PS and PSe ligands is described. Citing Literature Volume4, Issue102 October 1998Pages 1910-1916 RelatedInformation