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A kinetic and mechanistic study of the Baylis-Hillman reaction

1991; Elsevier BV; Volume: 32; Issue: 40 Linguagem: Inglês

10.1016/0040-4039(91)80098-q

1873-3581

Moira L. Bode, Perry T. Kaye,

Synthesis and Characterization of Heterocyclic Compounds

Reactions of acrylate esters with pyridinecarboxaldehydes, in the presence of 3-hydroxy-quinuclidine or 1,4-diazabicyclo[2.2.2] octane, have been followed by 1H NMR spectroscopy, and a mechanism which accommodates the kinetic data hase been presented.