Ein enantiomerenreiner alleno‐acetylenischer Makrocyclus: Synthese und Interpretation seiner herausragenden chiroptischen Eigenschaften
2009; Wiley; Volume: 121; Issue: 30 Linguagem: Alemão
10.1002/ange.200901240
ISSN1521-3757
AutoresJosé Lorenzo Alonso‐Gómez, Pablo Rivera‐Fuentes, Nobuyuki Harada, Nina Berova, François Diederich,
Tópico(s)Molecular spectroscopy and chirality
ResumoAngewandte ChemieVolume 121, Issue 30 p. 5653-5656 Zuschrift Ein enantiomerenreiner alleno-acetylenischer Makrocyclus: Synthese und Interpretation seiner herausragenden chiroptischen Eigenschaften José Lorenzo Alonso-Gómez Dr., José Lorenzo Alonso-Gómez Dr. Laboratorium für Organische Chemie, ETH Zürich, Hönggerberg, HCI, CH-8093 Zürich (Schweiz), Fax: (+41) 44-632-1109Search for more papers by this authorPablo Rivera-Fuentes, Pablo Rivera-Fuentes Laboratorium für Organische Chemie, ETH Zürich, Hönggerberg, HCI, CH-8093 Zürich (Schweiz), Fax: (+41) 44-632-1109Search for more papers by this authorNobuyuki Harada Prof., Nobuyuki Harada Prof. Department of Chemistry, Columbia University, New York, NY 10027 (USA) Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba, Sendai 980-8577 (Japan)Search for more papers by this authorNina Berova Prof., Nina Berova Prof. Department of Chemistry, Columbia University, New York, NY 10027 (USA)Search for more papers by this authorFrançois Diederich Prof., François Diederich Prof. [email protected] Laboratorium für Organische Chemie, ETH Zürich, Hönggerberg, HCI, CH-8093 Zürich (Schweiz), Fax: (+41) 44-632-1109Search for more papers by this author José Lorenzo Alonso-Gómez Dr., José Lorenzo Alonso-Gómez Dr. Laboratorium für Organische Chemie, ETH Zürich, Hönggerberg, HCI, CH-8093 Zürich (Schweiz), Fax: (+41) 44-632-1109Search for more papers by this authorPablo Rivera-Fuentes, Pablo Rivera-Fuentes Laboratorium für Organische Chemie, ETH Zürich, Hönggerberg, HCI, CH-8093 Zürich (Schweiz), Fax: (+41) 44-632-1109Search for more papers by this authorNobuyuki Harada Prof., Nobuyuki Harada Prof. Department of Chemistry, Columbia University, New York, NY 10027 (USA) Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba, Sendai 980-8577 (Japan)Search for more papers by this authorNina Berova Prof., Nina Berova Prof. Department of Chemistry, Columbia University, New York, NY 10027 (USA)Search for more papers by this authorFrançois Diederich Prof., François Diederich Prof. [email protected] Laboratorium für Organische Chemie, ETH Zürich, Hönggerberg, HCI, CH-8093 Zürich (Schweiz), Fax: (+41) 44-632-1109Search for more papers by this author First published: 08 July 2009 https://doi.org/10.1002/ange.200901240Citations: 39Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Eine einzigartige Kombination geometrischer und elektronischer Eigenschaften erklärt die bemerkenswert hohe Intensität der Cotton-Effekte in den Circulardichroismus-Spektren neuer enantiomerenreiner alleno-acetylenischer Makrocyclen (siehe Bild). Die enantiomerenreinen Makrocyclen (P,P,P,P)-(−)-1 (rot) und (M,M,M,M)-(+)-1 (blau) wurden über drei Stufen ausgehend von optisch reinen 1,3-Di-tert-butyl-1,3-diethinylallenen erhalten. Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. 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