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Formation of Two‐Dimensional Supramolecular Icelike Layer Containing (H 2 O) 12 Rings

2004; Wiley; Volume: 43; Issue: 11 Linguagem: Inglês

10.1002/anie.200353097

1521-3773

Bao‐Qing Ma, Hao‐Ling Sun, Song Gao,

Metal-Organic Frameworks: Synthesis and Applications

Water rings: Two novel water chains and layers have been observed in supramolecular solid states. The structures can be interconverted by varying crystallization conditions. The water layer consisting of fused (H2O)12 rings (see structure, O red, H blue) resembles ice Ih.