Comparison of the Geometries of 3,7,10-Tribenzyl-3,7,10-triaza[3.3.3]propellane, (1), 7,10-Dibenzyl-3-p-tolyl-3,7,10-triaza[3.3.3]propellane, (2), and 7,10-Dibenzyl-3-oxa-7,10-diaza[3.3.3]propellane, (3)

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Comparison of the Geometries of 3,7,10-Tribenzyl-3,7,10-triaza[3.3.3]propellane, (1), 7,10-Dibenzyl-3-p-tolyl-3,7,10-triaza[3.3.3]propellane, (2), and 7,10-Dibenzyl-3-oxa-7,10-diaza[3.3.3]propellane, (3)

1996; Wiley; Volume: 52; Issue: 6 Linguagem: Inglês

10.1107/s0108270195016039

ISSN

1600-5759

Autores

F. H. Herbstein, M. Kapon, G. M. Reisner,

Tópico(s)

Muon and positron interactions and applications

Resumo

Room-temperature crystal structures are reported for three analogous [3.3.3]propellanes. Compound (1), C29H33N3, is trigonal, (2), C29H33N3, triclinic and (3), C22H26N2O, orthorhombic. All three molecules have eclipsed conformations about the central conjoining bond, and the five-membered rings all have envelope conformations (Cs-m symmetry).

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Comparison of the Geometries of 3,7,10-Tribenzyl-3,7,10-triaza[3.3.3]propellane, (1), 7,10-Dibenzyl-3-p-tolyl-3,7,10-triaza[3.3.3]propellane, (2), and 7,10-Dibenzyl-3-oxa-7,10-diaza[3.3.3]propellane, (3)