Property-composition relationships for diesel and kerosene fuels
1985; Elsevier BV; Volume: 64; Issue: 4 Linguagem: Inglês
10.1016/0016-2361(85)90086-9
ISSN1873-7153
AutoresDavid Cookson, Jozef L. Latten, Ian Shaw, Brian E. Smith,
Tópico(s)Thermochemical Biomass Conversion Processes
ResumoA range of 18 diesel fuels and 21 kerosene fuels from mainly Australian petroleum and synthetic fuel sources, including coal, shale and peat, was investigated. Compositional details were defined as the weight per cent abundances of n-alkanes, branched plus cyclic saturates, single-ring aromatics, doublering aromatics and polynuclear aromatics, using both h.p.l.c. and 13C n.m.r. techniques. Relationships between fuel composition and a range of fuel properties were sought. Simple linear relationships between property values and compositional data were used. Explicit correlative expressions were derived using multiple linear regression analysis, with the coefficient of multiple determination, R2, indicating the quality of the fit between observed and calculated property values. In most cases good correlations were achieved. For diesels the properties investigated, with R2 values in parentheses, were: inverse specific gravity (0.99); 13C n.m.r. aromaticity (0.99); 1H n.m.r. aromaticity (0.88); cetane index (0.97); aniline point (0.96); diesel index (0.98); and FIA-measured aromatics content (0.77). For kerosenes the properties, with R2 values in parentheses, were: 13C n.m.r. aromaticity (0.98); 1H n.m.r. aromaticity (0.97); smoke point (0.88); and FIA-measured aromatics content (0.94). The results are shown to be of value in assessing the potential and limitations of hydrotreating as a process for upgrading synfuels.
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