Synthetic studies toward marine toxic polyethers (3) stereocontrol for segment-A1 of okadaic acid by means of oxymercuration and epoxydation
1985; Elsevier BV; Volume: 26; Issue: 42 Linguagem: Inglês
10.1016/s0040-4039(00)98902-0
ISSN1873-3581
AutoresMinoru Isobe, Yoshiyasu Ichikawa, Toshio Goto,
Tópico(s)biodegradable polymer synthesis and properties
ResumoSegment-A1 of okadale acid was synthesized from glucose via an acyclic stereocontrol for C-2 by means of oxymercuration. The stereochemistry was proven by comparison with S and R epoxides which were synthesized selectively by chelational and stereoelectronic effects, respectively.
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