Portal de Periódicos da CAPES

1H and13C NMR study of 2-substituted phenyl methyl sulphides

2000; Wiley; Volume: 38; Issue: 1 Linguagem: Inglês

10.1002/(sici)1097-458x(200001)38

1097-458X

S. Perumal, R. Chandrasekaran, S. Selvaraj, Mahesh Ganesan, David A. Wilson,

Synthesis and Characterization of Heterocyclic Compounds

Magnetic Resonance in ChemistryVolume 38, Issue 1 p. 55-57 Note 1H and 13C NMR study of 2-substituted phenyl methyl sulphides S. Perumal, Corresponding Author S. Perumal School of Chemistry, Madurai Kamaraj University, Madurai 625 021, IndiaSchool of Chemistry, Madurai Kamaraj University, Madurai 625 021, India===Search for more papers by this authorR. Chandrasekaran, R. Chandrasekaran School of Chemistry, Madurai Kamaraj University, Madurai 625 021, IndiaSearch for more papers by this authorS. Selvaraj, S. Selvaraj School of Chemistry, Madurai Kamaraj University, Madurai 625 021, IndiaSearch for more papers by this authorM. Ganesan, M. Ganesan School of Chemistry, Madurai Kamaraj University, Madurai 625 021, IndiaSearch for more papers by this authorD. A. Wilson, D. A. Wilson Department of Chemistry, University of Cardiff, Cardiff CF1 3TB, UKSearch for more papers by this author S. Perumal, Corresponding Author S. Perumal School of Chemistry, Madurai Kamaraj University, Madurai 625 021, IndiaSchool of Chemistry, Madurai Kamaraj University, Madurai 625 021, India===Search for more papers by this authorR. Chandrasekaran, R. Chandrasekaran School of Chemistry, Madurai Kamaraj University, Madurai 625 021, IndiaSearch for more papers by this authorS. Selvaraj, S. Selvaraj School of Chemistry, Madurai Kamaraj University, Madurai 625 021, IndiaSearch for more papers by this authorM. Ganesan, M. Ganesan School of Chemistry, Madurai Kamaraj University, Madurai 625 021, IndiaSearch for more papers by this authorD. A. Wilson, D. A. Wilson Department of Chemistry, University of Cardiff, Cardiff CF1 3TB, UKSearch for more papers by this author First published: 17 January 2000 https://doi.org/10.1002/(SICI)1097-458X(200001)38:1 3.0.CO;2-MCitations: 8AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract The 1H and 13C NMR spectra of seven 2-substituted phenyl methyl sulphides were measured and their chemical shifts assigned on the basis of two-dimensional NMR techniques such as H,H-COSY and C,H-COSY. The chemical shifts of these sulphides were correlated with the appropriate SCS values of monosubstituted benzenes. The influence of the variable substituent on the SCS values of the methylthio group at C-4 is explicable on the basis that the increased electronic repulsion and/or steric interaction between the 2-substituent and the methylthio group enhances the resonance interaction of the latter with the aromatic ring. Copyright © 2000 John Wiley & Sons, Ltd. Citing Literature Volume38, Issue1January 2000Pages 55-57 RelatedInformation