13 C NMR and 1 H NMR chemical shifts of bis(1,1‐dimethylethyl) disulfide and bis(1,1‐dimethylethyl) trisulfide and their oxide derivatives
1988; Wiley; Volume: 26; Issue: 9 Linguagem: Inglês
10.1002/mrc.1260260913
ISSN1097-458X
AutoresFillmore Freeman, Choonsun Lee,
Tópico(s)Organic Chemistry Cycloaddition Reactions
ResumoAbstract The 13 C NMR and 1 H NMR spectra of bis(1,1‐dimethylethyl) disulfide and bis(1,1‐dimethylethyl) trisulfide and their oxygenated derivatives, including sulfinothioic acid S ‐esters and sulfonothioic acid S ‐esters, have been studied. Deshielding β SO and β effects and shielding γ SO and γ effects are observed. The NMR spectra of tert ‐butyl polysulfides and the influences of sulfur atoms are also compared and discussed.
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