Highly Conductive PEDOT:PSS Nanofibrils Induced by Solution‐Processed Crystallization
2013; Volume: 26; Issue: 14 Linguagem: Inglês
10.1002/adma.201304611
ISSN1521-4095
AutoresNara Kim, Seyoung Kee, Seoung Ho Lee, Byoung Hoon Lee, Yung Ho Kahng, Yong‐Ryun Jo, Bong‐Joong Kim, Kwanghee Lee,
Tópico(s)Organic Electronics and Photovoltaics
ResumoCrystalline poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS) nanofibrils with an electrical conductivity of 4380 S cm-1 are formed via a solution process using H2SO4. The concentrated H2SO4 treatment induces a significant structural rearrangement of the PEDOT:PSS via a charge-separated transition mechanism, resulting in highly ordered and densely packed PEDOT:PSS nanofibrils. The PEDOT:PSS electrode shows a sheet resistance of 46 Ω sq-1 with 90% optical transmittance. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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