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Synthesis of gem -Bistriflates: Reaction of Aliphatic Aldehydes with Trifluoromethanesulfonic Acid Anhydride

1987; Thieme Medical Publishers (Germany); Volume: 1987; Issue: 01 Linguagem: Inglês

10.1055/s-1987-27839

1437-210X

Antonio García Martínez, Roberto Martínez Álvarez, Amelia Garcı́a Fraile, L. R. Subramanian, M. Hanack,

Synthesis and Reactivity of Sulfur-Containing Compounds

Reaction of aldehydes 1 with trifluoromethanesulfonic anhydride (2) in the presence of a base 3 or 4 at 0°C leads to gem-bistriflates 6 in good yields