Artigo Revisado por pares

Iron-Catalyzed Redox Radical Cyclizations of 1,6-Dienes and Enynes

2009; American Chemical Society; Volume: 12; Issue: 1 Linguagem: Inglês

10.1021/ol902562j

ISSN

1523-7060

Autores

Tsuyoshi Taniguchi, Naoya Goto, Asami Nishibata, Hiroyuki Ishibashi,

Tópico(s)

Catalytic C–H Functionalization Methods

Resumo

Treatment of 1,6-dienes and enynes with FeCl3 or Fe(Pc) in the presence of NaBH4 and air or O2 causes radical cyclization to give five-membered carbo or heterocyclic compounds, into which a halogen atom or hydroxyl group was introduced.

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