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Die thermische zersetzung der dimethylformamidkomplexe von einigen übergangsmetallen

1969; Pergamon Press; Volume: 31; Issue: 2 Linguagem: Inglês

10.1016/0022-1902(69)80472-0

1878-1225

Mira Glavaš, I. Ribar,

Chemical Reactions and Mechanisms

The thermal decomposition of 24 complexes of chromium(III), iron(III), iron(II), manganese(II), cobalt(II), nickel(II), copper(II), zinc(II) and cadmium(II) of N,N-dimethylformamide (DMF) were studied by thermogravimetry and differential thermal analysis. The thermal dissociation of MnCl2.2DMF, MnBr2.3DMF, CoCl2.3DMF, CoBr2.3DMF, CoJ2.6DMF, NiCl2.3DMF, NiBr2. 3DMF, NiJ2.6DMF, CuCl2.2DMF, CdCl2.2DMF and CdJ2.2DMF involved intermediate lower solvates. The desolvatations process of other complexes of dimethylformamide takes place in one step.