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The preparation and some properties of ferricinium trichloroferrate(II) and ferricinium tribromoferrate(II)

1970; Elsevier BV; Volume: 22; Issue: 1 Linguagem: Inglês

10.1016/s0022-328x(00)83090-9

1872-8561

Shaul M. Aharoni, Morton H. Litt,

Catalytic Cross-Coupling Reactions

The preparation and characterization of ferricinium trichloroferrate(II) and ferricinium tribromoferrate(II) are reported. The first salt crystallizes in the form of square, thin, platelets of d = 1.654 g/cm3. Its unit cell was determined to be orthorhombic with a = 14.49 Å, b = 14.52 Å, c = 13.38 Å and Z = 8. The second salt crystallizes in the form of thin parallelopiped platelets of d = 1.964 g/cm3. Its unit cell was determined to be also orthorhombic with a = 9.92 Å, b = 13.96 Å, c = 11.79 Å and Z = 4.