Alkoxyl radicals from alcohols. Spectroscopic detection of intermediate alkyl and acyl hypoiodites in the Suárez and Beebe reactions
1994; Elsevier BV; Volume: 35; Issue: 7 Linguagem: Inglês
10.1016/s0040-4039(00)79950-3
ISSN1873-3581
AutoresJohn L. Courtneidge, Janusz Lusztyk, Daniel Pagé,
Tópico(s)Catalysis and Oxidation Reactions
ResumoAcetyl hypoiodite and a number of alkyl hypoiodites have been characterized as intermediates in the conversion of alcohols into alkoxyl radicals under Suárez (photostimulated iodosobenzenediactetate/iodine reagent) and Beebe (photolysed acetyl hypoiodite/alcohol) conditions.
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