Stabilität und Kinetik bei Komplexbildungsreaktionen VIII. Polarographisches Verhalten einiger Zink‐ und Cadmium‐Komplexe
1958; Wiley; Volume: 41; Issue: 7 Linguagem: Inglês
10.1002/hlca.19580410716
ISSN1522-2675
AutoresKlaus Bernauer, D. Walz, S. Fallab,
Tópico(s)Electrochemical Analysis and Applications
ResumoAbstract A new polarographic method for determining complex‐stability constants is described. In solutions where the total metal‐ion concentration is equal to the ligand concentration, a relation has been found between the shift of the half‐wave potential and the degree of dissociation. The stability constants of some Cd 2+ and Zn 2+ complexes, determined by this method, are in agreement with those cited in the literature.
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