Formation of Phosphirenes by Phosphinidene Group-Transfer Reactions from (dtbpe)NiP(dmp) to Alkynes
2003; American Chemical Society; Volume: 22; Issue: 25 Linguagem: Inglês
10.1021/om0341754
ISSN1520-6041
AutoresRory Waterman, Gregory L. Hillhouse,
Tópico(s)Synthetic Organic Chemistry Methods
ResumoThe nickel phosphinidene complex (dtbpe)NiP(dmp) (1) has been found to undergo a general reaction with alkynes to produce phosphirenes. For PhC⋮CH, the olefin-bound nickel−phosphirene adduct (dtbpe)Ni{η2(C,C)-cyclo-CHC(Ph)P(dmp)} (2) has been isolated and crystallographically characterized.
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