Charge transfer theory and vibrational properties of the hydrogen bond
1973; Elsevier BV; Volume: 19; Linguagem: Inglês
10.1016/0022-2860(73)85267-6
ISSN1872-8014
AutoresH. Ratajczak, W.J. Orville-Thomas,
Tópico(s)Photochemistry and Electron Transfer Studies
ResumoAn extension of Mulliken's charge transfer theory leads to the following correlations: the change in the transition moment of the X—H stretching vibration with the enhancement of dipole moment, and the displacement of the X—H stretching frequency with the ionization of donors. Experimental data for a number of hydrogen-bonded complexes are in accord with these predictions.
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